Dry-Electrode Thick Coating Improvement | Coating Cracking Solutions

Powder Spraying Method

Dry-process electrode manufacturing is a solvent-free or minimal-solvent technology for electrode material preparation. Compared with wet coating methods, this approach eliminates solvent usage, reduces environmental impact, and minimizes impurity contamination during production. Primary dry-process techniques include powder spraying, binder fibrillation film-forming, and dry pressing.

1-Dry-Process Electrode Manufacturing Methods

①Powder Spraying Method:

Dry powders are directly sprayed onto substrates. High pressure applied to nozzle needles charges the fluidized powder particles. These charged particles then deposit onto grounded current collectors through electrostatic forces.

②Binder Fibrillation Film-Forming Method:

After uniformly mixing active materials and conductive additives, modified PTFE binder is introduced. Under intense shear forces, the mixture forms aggregates. The shear stress fibrillates PTFE microspheres into a matrix that mechanically locks electrode powders.

Dry Pressing Method:

Pre-mixed electrode materials, conductive additives, and dry PVDF powder are compressed onto etched aluminum foil, followed by thermal calendaring to produce dry-process electrodes.

2-Crack Mitigation Mechanisms in Thick Coatings

①Enhanced Dispersion Uniformity

Dry mixing ensures homogeneous distribution of active materials, conductive agents, and PTFE binders. This eliminates solvent-induced composition segregation, thereby reducing localized stress concentrations.

②Solvent-Free Processing

The absence of solvent evaporation prevents electrode delamination, maintaining coating integrity and significantly reducing crack formation risks.

3-Technical Advantages & Challenges

Advantages

  • Environmentally friendly process
  • Enhanced interfacial compatibility
  • Higher production efficiency (30-50% faster than wet methods)
  • Increased active material loading capacity
  • Ideal for high-energy-density battery manufacturing

Challenges

  • Non-uniform coating in electrostatic spraying (limited to lab-scale)
  • Strict environmental controls required for PTFE fibrillation (humidity <30%)
  • Severe roller surface wear during calendaring (tooling life reduced by 40-60%)

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